Simultaneous and time resolved X-ray scattering and differential Scanning calorimetry experiments (SAXS/WAXD/DSC) using synchrotron radiation. Polímeros. Kaisersberger ()7 analisou com a calorimetria diferencial de varredura, DSC, os processos de fusão, cristalização e oxidação de óleos. Kovalski ()5 e. (PMA) foi investigada por calorimetria diferencial de varredura no modo modulado (DSC-modulado) e por espalhamento de raios-x de baixo ângulo ( SAXS).

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Calorimetria de varredura diferencial (DSC)

Environmental Stress Cracking of Plastics. This is due to the sample undergoing a change in heat capacity ; no formal phase change occurs. The reaction vessel, equipped with stirring, was kept in a water bath maintained vvarredura 80 o C.

Views Read Edit View history. With increasing crosslink density, the fraction of interface increased only slightly. Services on Demand Journal. Planta MedicaStuttgart, v.

For monodisperse particles 7 the scattering intensity is given by Eq. Calorimetric and spectroscopic studies of the thermotropic phase behavior of the n -saturated 1,2- diacylphosphatidylglycerols.

For laboratories where maximizing instrument up-time is critical to its daily performance. SAXS samples, approximately 0. In this technique it is the heat flow to the sample and reference that remains the same rather than the temperature. D Cp is proportional to the weight fraction of the component concerned 4.


This observation will be discussed again later in this paper. Lewis PR, Gagg C Malvern Panalytical Platinum Plan For laboratories where maximizing instrument up-time is critical to its daily performance. An oscillation amplitude of 1. This yields precise information on the weight fraction of the interface in such particles.

A model has to be used to predict this. Then, 25g MA and a solution of AP 0. Likewise, as the sample undergoes exothermic processes such as crystallization less heat is required to raise the sample temperature.

Polymer38 Calorimetria diferencial de varredura. Any oxidation that occurs is observed as a deviation in the baseline.

Calorimetria de varredura diferencial (DSC) para estudo da estabilidade da proteína

For the analysis of the SAXS data, a simple concentration gradient model for the interfacial structure was used.

Temperature and cell constant were calibrated using an empty pan 20mg and a standard indium sample 10mg TA-Instrumentsand the baseline was established by running an empty pan 20mg. This is known as the crystallization temperature T c. Now the results shown in Figure 2 will be reconsidered. An invaluable tool for a detailed thermodynamic characterization of macromolecules and their interactions”.


After the MA monomer addition was complete, the reaction was allowed to post-react for 1 h to ensure the completion of polymerization. A curva de Arrhenius, considerando ordem zero, fica sendo dada conforme a Figura 8. Whether less or more heat must flow to the sample calorimeteia on whether the process is exothermic or endothermic.

MicroCal PEAQ-DSC Automatizado

Comparing the model and experimental results see Figure 3only the SAXS data for latex5 are similar to that varedura by the core-shell model. It is clear that M-TDSC can only provide information on the weight fraction of interface in structured latices, but not on morphology.

For an immiscible polymer blend, the total D Cp is the sum of the D Cp values of the two constituent polymers 4.